The film's story begins when Arata inadvertently touches "Hermes Apocrypha," Lilith's Grimoire. Suddenly, he is enveloped by a bright white light, and a girl appears before him. She calls herself Lilim, and treats both Arata and Lilith as her parents. At the same time she appears, something changes in the world. The forbidden Eternal Library awakens. In the Library is sealed the ultimate culmination of Alchemy, the White Demon Lord. The White Demon Lord plots to eliminate Arata and the Trinity Seven to usurp the position of Demon Lord. Bristling with untold power, the White Demon Lord attacks Arata, and triggers a desperate crisis where Arata and the Trinity Seven must save the world in this last battle.
松岡禎丞
as Arata Kasuga (voice)
原由実
as Lilith Asami (voice)
日高里菜
as Lilim (voice)
島﨑信長
as Last Trinity (voice)
市道真央
as Anastasia L (voice)
柚木涼香
as Akio Fudou (voice)
内田彩
as Arin Kannazuki (voice)
佐倉綾音
as Levi Kazama (voice)
村川梨衣
as Yui Kurata (voice)
東山奈央
as Sherlock Lieselotte (voice)
日笠陽子
as Mira Yaman (voice)
三木眞一郎
as Gakuenchou Biblia (voice)